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MARC状态:审校 文献类型:西文图书 浏览次数:133

题名/责任者:
Pincer compounds : chemistry and applications / edited by David Morales-Morales.
出版发行项:
Amsterdam, Netherlands : Elsevier, [2018]
ISBN:
9780128129319
载体形态项:
xvii, 736 pages : illustrations ; 28 cm.
附加个人名称:
Morales-Morales, David, editor.
论题主题:
Organometallic compounds.
论题主题:
Organometallic chemistry.
论题主题:
SCIENCE / Chemistry / Organic.
论题主题:
Organometallic chemistry.
论题主题:
Organometallic compounds.
中图法分类号:
O627
书目附注:
Includes bibliographical references and index.
内容附注:
1. Chiral pincer complexes for asymmetric reactions -- 2. Well-defined iron and manganese pincer catalysts -- 3. The pincer complexes of Group 13-15 elements: recent developments -- 4. Reduction of CO2 mediated or catalyzed by pincer complexes -- 5. Mechanistic insights and computational prediction pincer complexes for catalytic hydrogenation and dehydrogenation reactions -- 6. Hydrogenation and dehydrogenation reactions catalyzed by iron pincer compounds -- 7. Actinide pincer chemistry: a new frontier -- 8. Complexes of NHC-based CEC pincer ligands: structural diversity and applications -- 9. Transition metal pincer complexes with chiral imidazoline donor(s): synthesis and asymmetric catalysis -- 10. Chral NCN pincer-type catalysts having bis(imidazoline)s -- 11. Transition metal pincer complexes with a central sp3-hybridized carbon atom -- 12. CCC-NHC pincer compleses: synthesis, applications, and catalysis --^13. Metal pincer complexes in aqueous media: approaches with water as solvent, reagent, and molecular hydrogen storage -- 14. Pincers based on dicarboxamide and dithiocarboxamide functional groups -- 15. pincer complexes of iron and their application in catalysis -- 16. Osmium complexes with POP pincer ligands -- 17. Pincer carbenoid complexes withj late transition metals: synthesis, electronic structure, and reactivity -- 18. Pincer iridium and ruthenium complexes for alkane dehydrogenation -- 19. Silicon-based pincers: trans influence and functionality -- 20. Transition metal complexes with anionic sulfur-based pincer ligands -- 21. Metalation and transmetalation chemistry of pyridine- and aryl-linked Bis-NHC pincer ligands -- 22. Unsymmetrical pincer palladacycles synthesis and reactivity -- Benzene-derived organometallic pincer complexes bearing six-membered metallacycles and up -- Chemistry of Mn and Co pincer compounds --^25. Selective deuteration of organic compounds catalyzed by ruthenium pincer complexes -- 26. [sigma]-organometallic chemistry with 2.6-bis(imino)pyridine ligands: new pathways to innovative pincer architectures -- 27. Use of pincer compounds as metal-based receptors for chemosensing of relevant analytes -- 28. Advances in the design and application of redox-active and reactive pincer ligands for substrate activation and homogeneous catalysis -- 29. The chemistry of bisphosphomide and 1,2-phenylenediamine based PBP pincer transition metal complexes and catalytic applications -- 30. Ligand-introduction synthesis of NCN-pincer complexes and their chemical properties -- 31. Pincer complexes of gold: an overview of synthesis, reactivity, photoluminescence, and biological applications -- 32. Semirigid pincer-like SiPSi ligands: classical versus nonclassical coordination modes at Ru, Rh, Ir, and Pt -- 33. Conclusions and personal comment.
摘要附注:
Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research-from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen's The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry-from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications.
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